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Earth’s inner core is predominantly composed of solid iron (Fe) and displays intriguing properties such as strong shear softening and an ultrahigh Poisson’s ratio. Insofar, physical mechanisms to explain these features coherently remain highly debated. Here, we have studied longitudinal and shear wave velocities of hcp-Fe (hexagonal close-packed iron) at relevant pressure–temperature conditions of the inner core using in situ shock experiments and machine learning molecular dynamics (MLMD) simulations. Our results demonstrate that the shear wave velocity of hcp-Fe along the Hugoniot in the premelting condition, defined asT/T_m(T_m: melting temperature of iron) above 0.96, is significantly reduced by ~30%, while Poisson’s ratio jumps to approximately 0.44. MLMD simulations at 230 to 330 GPa indicate that collective motion with fast diffusive atomic migration occurs in premelting hcp-Fe primarily along [100] or [010] crystallographic direction, contributing to its elastic softening and enhanced Poisson’s ratio. Our study reveals that hcp-Fe atoms can diffusively migrate to neighboring positions, forming open-loop and close-loop clusters in the inner core conditions. Hcp-Fe with collective motion at the inner core conditions is thus not an ideal solid previously believed. The premelting hcp-Fe with collective motion behaves like an extremely soft solid with an ultralow shear modulus and an ultrahigh Poisson’s ratio that are consistent with seismic observations of the region. Our findings indicate that premelting hcp-Fe with fast diffusive motion represents the underlying physical mechanism to help explain the unique seismic and geodynamic features of the inner core.

 

The interacting dark energy (IDE) model, which considers the interaction between dark energy and dark matter, provides a natural mechanism to alleviate the coincidence problem and can also relieve the observational tensions under the ΛCDM model. Previous studies have put constraints on IDE models by observations of cosmic expansion history, cosmic microwave background, and large-scale structures. However, these data are not yet enough to distinguish IDE models from ΛCDM effectively. Because the non-linear structure formation contains rich cosmological information, it can provide additional means to differentiate alternative models. In this paper, based on a set of N-body simulations for IDE models, we investigate the formation histories and properties of dark matter haloes and compare with their ΛCDM counterparts. For the model with dark matter decaying into dark energy and the parameters being the best-fitting values from previous constraints, the structure formation is markedly slowed down, and the haloes have systematically lower mass, looser internal structure, higher spin, and anisotropy. This is inconsistent with the observed structure formation, and thus this model can be safely ruled out from the perspective of non-linear structure formation. Moreover, we find that the ratio of halo concentrations between IDE and ΛCDM counterparts depends sensitively on the interaction parameter and is independent of halo mass. This can act as a powerful probe to constrain IDE models. Our results concretely demonstrate that the interaction of the two dark components can affect the halo formation considerably, and therefore the constraints from non-linear structures are indispensable.

 

Antimicrobial pentatopic 2,2′:6′,2′′-terpyridines that form 3-D supramolecular hexagonal prisms with Cd 2+ through coordination driven self-assembly can be entrapped by lipid discoidal bicelles, composed of 1,2-dipalmitoyl- sn-glycero -3-phosphocholine, 1,2-dihexanoyl- sn-glycero -3-phosphocholine and 1,2-dipalmitoyl- sn-glycero -3-phospho-(1′-rac-glycerol) lipid, forming a well-defined nanocomplex. Structural characterization performed by very small angle neutron scattering, small angle X-ray scattering and transmission electron microscopy suggests that the hexagonal prisms are preferably located at the rim of bicellar discs with the hexagonal face in parallel with the bilayers, instead of face-to-face stacking. Such a configuration reduces the π−π interaction and consequently enhances the fluorescence emission. Since novel supramolecules were reported to have antibiotic functions, this study provides insight into the interactions of antimicrobial supermolecules with lipid membranes, leading to potential theranostic applications. 

The striking resemblance of high multiplicity proton-proton (pp) collisions at the LHC to heavy ion collisions challenges our conventional wisdom on the formation of the quark-gluon plasma (QGP). A consistent explanation of the collectivity phenomena in pp will help us to understand the mechanism that leads to the QGP-like signals in small systems. In this study, we introduce a transport model approach connecting the initial conditions provided by PYTHIA8 with subsequent AMPT rescatterings to study the collective behavior in high energy pp collisions. The multiplicity dependence of light hadron productions from this model is in reasonable agreement with the pp$$\sqrt{s}=13$$$\sqrt{s}=13$TeV experimental data. It is found in the comparisons that both the partonic and hadronic final state interactions are important for the generation of the radial flow feature of the pp transverse momentum spectra. The study also shows that the long range two particle azimuthal correlation in high multiplicity pp events is sensitive to the proton sub-nucleon spatial fluctuations.